摘要：测试一系列的丙烯酸树脂乳液，并对其流变特性进行了研究。分别考察了稳态和动态测试条件下的影响，根据实验动态测试结果表明，随着角频率的增加，体系储能模量和损耗模量随之上升。随着固含量的增加，采用平板会导致体系的粘弹性能减弱。稳态测试结果表明，随着剪切速率的增大，体系的表观黏度随之下降，体系呈现出假塑性流体剪切稀化的流变特征。根据试验结果，制备了汽车底垫的底涂和中涂试剂，以及漆皮试剂，对几种不同的丙烯酸树脂乳液进行测试，选择最合适的丙烯酸树脂乳液。20121
关键词：丙烯酸树脂；流变；粘弹性；剪切黏度
 Rheology test of acrylic resin emulsions
Abstract:Using the plate method to test a series of acrylic resin emulsion and rheological properties were studied. Were investigated under the influence of solid content, steady-state and dynamic test conditions, the experimental dynamic test results show that with the increase of the angular frequency of the system storage modulus and loss modulus rise. As the solids content increases, the viscoelastic properties of the system will lead to weakening. Steady-state test results show that with increasing shear rate, the apparent viscosity of the fall, the system exhibits pseudoplastic rheological fluid shear thinning characteristics. According to the results, the preparation of the car and the bottom pad primer coating agent, and Patent reagent of several different acrylic resin emulsion is tested to select the most suitable acrylic resin emulsion.
Keywords：Acrylic resin；rheological；viscoelastic；Shear viscosity
目录
1 绪论    5
1.1丙烯酸树脂行业简况    5
1.2 丙烯酸树脂乳液的制备方法    7
1.2.1 传统的多元单体共聚,接技和交联法    7
1.2.2核壳乳液聚合技术    7
1.2.3微粒化技术    7
1.2.4 交联技术    8
1.3 丙烯酸树脂乳液在皮革中的应用    8
    1.4丙烯酸树脂乳液的流变性    9
    1.4.1流变性    9
1.4.2流变学在工业生产中的应用    10
    1.4.3 丙烯酸树脂乳液的流变性    11
2 实验部分    13
2.1 主要化工原料    13
2.2 仪器设备    14
2.3实验配方    15
2.4皮革涂饰剂的流变性测试    17
    2.4.1稳态剪切扫描.18                                      
    2.4.2动态剪切扫描.19
3 结果与讨论    20
3.1丙烯酸树脂乳液线性粘弹区的确定    20
3.2 操作平台的选择    21
3.3丙烯酸树脂乳液的测试    22
    3.3.1稳态剪切扫描.22
        3.3.2利用 Cross 模型对漆皮试剂的稳态曲线进行分析.23
    3.3.3动态剪切扫描.24
    3.4汽车底垫底涂与中涂样品测试    24
        3.4.1汽车底垫底涂试剂的流变25
        3.4.2汽车底垫中涂的流变性能.26
3.5 漆皮样品的测试    27
    3.5.1稳态剪切扫描.27
        3.5.2利用 Cross 模型对漆皮试剂的稳态曲线进行分析.28
        3.5.3动态剪切扫描.29 丙烯酸树脂乳液的流变性测试+文献综述:http://www.751com.cn/fanwen/lunwen_11772.html