摘要：纳米TiO2光催化技术是一种具有高效、节能、无毒和低成本的环保技术。TiO2光催化剂在废水处理、污染物降解和空气净化等领域具有广阔的应用前景。本文以钛酸四丁酯（TBOT）为原料，采用溶胶-凝胶法制备TiO2微球。继而利用氧化石墨烯表面上的含氧官能团（-COOH，-OH）与TiO2微球表面的羟基基团（-OH）之间脱水缩合，探索了以TiO2微球为核，氧化石墨烯和纳米Cu为壳制备具有核壳结构的TiO2微球/氧化石墨烯/纳米Cu复合材料。利用扫描电子显微镜（SEM）、X射线衍射技术（XRD）、固体紫外漫反射光谱(DRS)和荧光光谱（FL）对所得产物的结构和性能进行了初步表征，结果显示所制备的TiO2微球直径为800-1500 nm，TiO2复合微球对可见光的吸收范围明显宽于纯TiO2，说明其对可见光的利用率较高。22189
毕业论文关键词：氧化石墨烯；TiO2微球；纳米Cu；制备；核/壳结构
Synthesis of TiO2 microspheres                  
Abstract:Nano-TiO2 photocatalysis is an energy-saved, high efficiency, low cost and non-toxicity environmental technology.TiO2 photocatalyst has broad application perspect ive in wastewater treatment,air purification and Degradation of pollutants. This article describes the TiO2 powder was prepared by sol-gel method with tetra-n-butyl titanate（TBOT）as raw material. The encapsulated process of this study is mainly relies on the direct dehydration condensation reaction between the oxygen-containing functional groups (–COOH, -OH) on the surface of graphene oxides and the hydroxyl groups (–OH) on TiO2 microspheres surface. Then, we explored the synthesized graphene oxide and nano-Cu encapsulated TiO2 core/shell structures composite microspheres. The morphology and activity of the as-prepared samples were well characterized by field-emission scanning electron microscope(SEM), X-ray diffraction technique(XRD), optical diffuse-reflection spectra(DRS) and Fluorescence Spectrophotometer(FL). SEM measurements reveal that the diameter of the as-prepared TiO2 microsphere is about 800-1500 nm. DRS results indicate that comparison with that of the pure TiO2 microspheres, the absorption intensity in the visible region was much enhanced after GO and nano-Cu encapsulated on the surface of the TiO2 microspheres.
Keywords:Graphene oxide; TiO2; nano-Cu; prepared;core/shell structure
目录
中文摘要    1
英文摘要    2
1 前言    5
1.1 纳米TiO2的简介    5
1.2 二氧化钛半导体光催化材料研究的目的和意义    6
1.3 TiO2的光催化原理    7
1.4 制备纳米二氧化钛的不同方法    8
1.4.1 模板法    8
1.4.2 溶胶-凝胶法    8
1.4.3 水热法    8
1.4.4 自组装法    8
1.5 溶胶-凝胶法制备TiO2的特点    9
2 实验部分    10
2.1 化学试剂    10
2.2 化学仪器    10
2.3 TiO2微球的制备    11
2.4 氧化石墨烯包覆的TiO2微球的制备    12
2.5 纳米铜负载的氧化石墨烯包覆的TiO2微球的制备。    13
2.6 掺C的TiO2微球的制备    13
2.7 物理表征    13
3 结果与讨论    14
3.1 TiO2微球结构和形貌分析    14
3.1.1 TiO2微球的XRD图谱分析    14
3.1.2 TiO2形貌分析    15
3.2 氧化石墨烯、纳米铜包覆的TiO2核壳结构微球的制备和表征    15
3.2.1 氧化石墨烯、纳米铜包覆的TiO2核壳结构微球的XRD图谱分析    16 TiO2微球的合成+文献综述:http://www.751com.cn/huaxue/lunwen_14700.html