摘要：用硼氢化钠，氯化亚锡乙醇溶液，氨水，在乳液体系中反应生成纳米有机锡，最佳的反应条件是：硼氢化钠与氯化亚锡的摩尔比为2.52:1，反应时间为2h，反应温度为45℃，反应得到的产物的最高产率为79.9%。利用红外光谱仪分析产物，并在环-块式摩擦磨损试验机和四球试验机上，测定了纳米有机锡添加到基础油后的摩擦磨损性能及纳米有机锡的添加量对这些性能的影响进行了考察，结果表明，含纳米有机锡1.5%（wt%）时，抗磨效果最佳。测定基础油、添加1.5%（wt%）纳米有机锡的基础油及添加T202的基础油三者的最大无卡咬负荷PB，结果表明添加T202后基础油的PB值最大。最后测定纳米有机锡与T202复配后的摩擦化学性能以及两者的添加量对基础油的摩擦磨损性能的影响，结果表明，当添加1.5%（wt%）纳米有机锡时和添加1%（wt%）T202复配时，润滑油的抗磨效果最佳。24622
毕业论文关键词：纳米有机锡；乳液法；T202；润滑油；抗磨减
Preparation of nanometer tin compound and chemical properties of the friction
Abstract: The nano-organic-tin is the reaction of sodium borohydride, ethanol solution of stannous chloride and ammonia water under the micro-nano-emulsion system. The best reaction condition is when the mole ratio of sodium borohydride and ethanol solution of stannous chloride is 2.52:1,the reaction time is 2h, the reaction temperature is 45℃ and the most prolific rate of the product is 79.9%.Using the infrared spectrometer product, and in the ring-pieces type friction and wear tester and four ball, determinate of nano-organic-tin added to base oil and the friction and wear properties after the addition of nano-organic-tin on these properties were investigated, results showed that when the content of nano-organic-tin is 1.5%(wt%),wear the best. Determine the largest non-card bite load PB of base oil, adding 1.5%(wt%) of nano-organic-tin in the base oil and adding the T202's base oil, the results show that the base oil after adding T202,its PB is maximum. Finally, determine the friction chemical about the compound of nano-organic-tin and T202 and the friction and wear performance impact of these two adding amount of base oil, the results show that when add 1.5%(wt%) of nano-organic-tin and add 1 %(wt%) of T202 compound, the anti-wear of lubricating oil gains its best effects.
Key words: nano-organic- tin; microemulsion;T202;lubricants;friction and wear
 目  录
1 绪论    1
1.1纳米材料的性质    1
1.1.1表面效应    1
1.1.2体积效应    2
1.1.3磁学性质    2
1.1.4电学性质    2
1.1.5 热学性质    2
1.2纳米粒子的种类和制备方法    3
1.3纳米粒子的表面修饰    3
1.4润滑剂    3
1.4.1润滑剂的作用    4
1.4.2润滑机理    4
1.4.3润滑剂的发展    4
1.5润滑油添加剂    5
1.5.1润滑油添加剂的工作原理    5
1.5.2润滑油添加剂的开发    6
1.5.3添加剂的作用    6
1.6 润滑材料及其添加剂的抗磨减摩机理    7
1.6.1 摩擦磨损产生的原因    7
1.6.2 纳米粒子抗磨减摩机理    7
1.7课题研究的意义    8
1.8本课题的创新点    8
2纳米有机锡的制备及与T202复配的摩擦化学特性    9
2.1实验试剂与实验设备    9
2.1.1 实验试剂    9
2.1.2 实验设备    9
2.2实验仪器介绍    9
2.2.1四球机    9 油酸修饰纳米有机Sn的制备及摩擦化学特性的研究:http://www.751com.cn/huaxue/lunwen_18216.html