摘要：论文将油菜秸秆纤文在不同的微波条件下进行预处理，研究微波处理对液化效率的影响，利用FTIR仪器分析表征液化产物的结构，并通过测定液化过程中液化产物的酸值、羟值和粘度来研究液化产物的物理性质。结果表明：在微波功率340 W，处理时间3 min，浓硫酸（H2SO4）催化下，秸秆纤文在聚乙二醇（Polyethylene glycol）和丙三醇（Glycerol）中液化，秸秆纤文液化的最佳工艺条件为：液固比为6：1，反应时间40 min，温度160 ℃，PEG含量为75%，催化剂用量2%。在该条件下所得残渣率为1.5%。通过与未处理的油菜秸秆粉末液化对比，处理后液化时间可由120 min缩短至40 min，硫酸的用量有5%降低至2%。37610
毕业论文关键词：油菜秸秆；液化；微波预处理；
Synthesis and characterization of rape straw polyether polyol
Abstract: The microwave Pre-treatment of rape straw fibers in water under different conditions was also used to study effect of microwave treatment on the efficiency of liquefaction. And liquefied product structure is characterized by FTIR methods of instrumental analysis. Through the infrared liquefied product structure were measured, and the acid value of liquefaction products, viscosity and hydroxyl value. The results show that, This dissertation was used to evaluate the Polyhydroxy alcohol liquefaction reaction of rape straw fiber with concentrate sulfuric acid (H2SO4) as the catalyst, Polyethylene glycol (PEG) and ethylene glycol (EG) as the liquefaction reagent. The index values showed that the optimum reaction conditions were that, liquid-solid ratio was6:1, temperature of liquefaction was 160℃,reaction time was 40min, PEG content was 75%, the percentage of concentrated sulfuric acid (H2SO4) was 2wt%. Under these conditions, the content of Rape residue was only1.5%, Comparison of the liquefaction of rape straw with untreated rape, the liquefaction time was shortened from 120min to 40min, the amount of sulfuric acid catalyst decreased from 5% to 2%.
Key words: rape straw; liquefaction; microwave pretreatment
目 录
1 绪论 1
1.1 植物纤文基本组成及结构特征 1
1.1.1纤文素 1
1.1.2半纤文素 2
1.1.3木质素 2
1.2 植物纤文预处理技术研究进展 3
1.2.1纤文素物理预处理方法 3
1.2.2纤文素化学预处理方法 5
1.2.3生物处理 5
1.3植物纤文液化方法研究进展 5
1.3.1高温高压液化 6
1.3.2酶法液化 6
1.3.3溶剂液化 6
1.4 现有问题 8
1.5 选题依据 8
1.6 立题的目的和意义 8
1.7 研究内容和目标 8
1.8 创新性 9
2 实验部分 10
2.1实验试剂 10
2.2实验方法 10
2.2.1微波预处理油菜秸秆 10
2.2.2油菜秸秆粉末液化 10
2.3分析表征 11
2.3.1油菜秸秆纤文基本性质测定 11
2.3.2液化产物的残渣率测定 11
2.3.3酸值的测定 12
2.3.4羟值的测定 12
2.3.5粘度的测定 13
2.3.6红外光谱仪 13
3 结果与讨论 15
3.1微波处理对纤文液化反应过程及产物的影响 15
3.1.1微波处理功率对液化残渣率的影响 15
3.1.2微波处理时间对液化残渣率变化趋势的影响 15
3.1.3油菜秸秆液化中不同液固比对残渣率的影响 16 油菜秸秆基聚醚多元醇的合成与表征:http://www.751com.cn/cailiao/lunwen_36412.html